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Dimethyl itaconate may be used in functionalization of isotactic poly(propylene). Dimethyl itaconate undergoes enantioselective Rh(I)-catalyzed hydrogenation which can be enhanced by appropriate choice of substituents on aromatic ring of (1,2-diarylphosphinoxy)cyclohexane. It was used in crosslinking of polyesters: poly(isosorbide itaconate)and poly(isosorbide itaconate-co-succinate).
Dalton Trans. 2009 Sep 7;(33):6528-35.
Chiral diphosphinites derived from 2,2-biphosphole as a new class of stereodynamic ligands for enantioselective hydrogenation
Dimethyl itaconate purchased from AbMole
| Molecular Weight | 158.15 |
| Formula | C7H10O4 |
| CAS Number | 617-52-7 |
| Solubility (25°C) | Slightly soluble in water |
| Storage | 2-8°C, dry, protect from light, sealed |
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